Once you let it warm back up, the edges of the resin will firm up. You might need to wait a day or two for the complete full cure time, but the edges will be firm if there wasnt anything amiss with the cure (i.e. incorrect ratio, too many inclusions, etc). The freezer method shouldnt have caused any lasting effect.
One of the molds I routinely use, a cheap plastic paint pallet, is inflexible and so I use the freezer method all the time. With the pallet, I dont even need to use a release agent, just the freezer. I also use the freezer with other stubborn releases, too.